مشخصات پژوهش

صفحه نخست /Novel MCM-41 based ...
عنوان Novel MCM-41 based chromogenic probe: Highly selective and sensitive upon cyanide ion over other interfering anions in water
نوع پژوهش مقاله چاپ‌شده
کلیدواژه‌ها Colorimetric chemosensor, Cromogenic probe, Cyanide ion, MCM-41, Schiff base, Solid sensor.
چکیده A new molecular anion receptor, HL, was synthesized via condensation reaction of 2-hydroxy-3-methoxy-5-((2,4-dichlorophenyl)diazenyl)benzaldehyde, L, with 3-aminopropyl triethoxysilane in EtOH. Moreover, a novel hybrid organic-inorganic chromogenic material (HL/MCM-41) was also prepared by covalently anchoring of HL onto MCM-41 scaffold. The prepared chromogenic probe was proved using various characterization techniques such as XRD, FE-SEM, BET, TGA, and FT-IR. Remarkably, HL/MCM-41 act as a solid chromogenic probe and shows unique and rapid sensitivity towards CN−, over other interfering anions such as H2PO4ˉ, AcOˉ, Fˉ, Clˉ, and Brˉ, in water and could it easily visualized through naked eye detection even at 5×10-3 molL-1 without any spectroscopic instrumentation.
پژوهشگران مژگان زنده دل (نفر سوم)، حمید خانمحمدی (نفر دوم)، مرجان فرامرزی (نفر اول)