مشخصات پژوهش

عنوان	Synthesis and computational studies of new metallo-phthalocyanines bearing dibenzoxanthenes and evaluation of their optical properties in solution and solid PMMA/ZnPc/Al nanocomposite lms
نوع پژوهش	مقاله چاپ‌شده
کلیدواژه‌ها	Soluble metallophthalocyanine, dibenzoxanthene, aggregation, nanocomposite lm, geometry optimization
چکیده	New thermally stable metallo-phthalocyanines bearing dibenzoxanthenes as highly organo-solubilizing aro- matic hydrocarbon substituents were successfully prepared by cyclotetramerization of corresponding phthalonitriles with anhydrous metal salts [Zn(CH3COO)2 and NiCl2 ] in the presence of a catalytic amount of DBU in 2-(dimethylamino) ethanol. All of these phthalocyanines are soluble in some organic solvents such as DMF, DMSO, THF, CH2 Cl2 , and CHCl3 . Then we successfully prepared the poly(methyl methacrylate) (PMMA)/ZnPc/Al nanocomposite _lms by incorporating Al nanoparticles into a transparent PMMA/ZnPc matrix. The structure and morphology of nanocom- posite _lms were studied using X-ray diffraction and scanning electron microscopy. The optical absorption spectra of PMMA/ZnPc/Al nanocomposite _lms showed red shifting in the Q-band in the polymeric matrix. The geometrical structure of two phthalocyanines was investigated at the RHF/3-21G* computational level.
پژوهشگران	پیمان ذوالقرنین (نفر ششم به بعد)، محمد سلیمان نژاد (نفر ششم به بعد)، زینب دلیرنسب (نفر ششم به بعد)، اعظم خدادادی (نفر پنجم)، میثم سوری نیا (نفر سوم)، زینب جعفرزاده دیزآبادی (نفر دوم)، علیرضا کریمی (نفر اول)، اکبر زنده نام (بازنشسته) (نفر چهارم)