عنوان
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Efficient oxidative dehydrogenation of dihydropyrimidinones and thiocyanation of aromatic compounds using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane as the oxidant
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نوع پژوهش
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مقاله چاپشده
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کلیدواژهها
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Dehydropirimidinones, Oxidative dehydrogenation, Thiocyanation, 1,1,2,2-Tetrahydroperoxy-1,2-diphenylethane, Pyrimidinones
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چکیده
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A new, efficient and mild approach for the oxidative dehydrogenation of dihydropyrimidinones and thiocyanation of aromatic compounds using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane (THPDPE) as a terminal oxidant was developed. Initially, various substrates bearing different electron-donating and electron-releasing functionalities were synthesized, and next under the optimized reaction conditions the desired products were yielded after an easy work-up. All of the reactions proceeded in short reaction times, and 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane (THPDPE) proved its potential to yield the desired products in high yields.
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پژوهشگران
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شیرین ناصری فر (نفر سوم)، امیر عزیزی (نفر دوم)، کاوه خسروی (نفر اول)
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