مشخصات پژوهش

صفحه نخست /A new trinuclear N–N bridged ...
عنوان A new trinuclear N–N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine
نوع پژوهش مقاله چاپ‌شده
کلیدواژه‌ها Trinuclear copper complex Schiff base ligands Magnetic properties Hydrazine Asymmetric ligands
چکیده In this paper we report the synthesis of an asymmetric Schiff base ligand derived from hydrazine and its Cu(II) trinuclear coordination complex, [Cu3(HYDRAV)2Cl2] (HYDRAV-Cu). The ligand HYDRAVH2 and the Cu(II) complex HYDRAV-Cu have been crystallographically characterized. HYDRAVH2 contains a fluorescent naphthyl group and emission properties of both HYDRAVH2 and HYDRAV-Cu are reported. The magnetic properties of HYDRAV-Cu have been investigated. Hydrazine is an excellent precursor for asymmetric Schiff base ligands that afford antiferromagnetic coupling as shown here for HYDRAV-Cu.
پژوهشگران کارولینا سانودو (نفر سوم)، حمید خانمحمدی (نفر دوم)، سمیرا قلی زاده دوگاهه (نفر اول)