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Mohammad Yaser Masoomi

Mohammad Yaser Masoomi

Academic rank: Assistant Professor
ORCID: https://orcid.org/0000-0003-1329-5947
Education: PhD.
ScopusId: 36927960900
Faculty: Science
Address: Arak University
Phone:

Research

Title
Application of Two Cobalt-Based Metal-Organic Frameworks as Oxidative Desulfurization Catalysts
Type
JournalPaper
Keywords
Oxidative Desulfurization , Catalyst, Metal-Organic Frameworks
Year
2015
Journal Inorganic Chemistry
DOI
Researchers Mohammad Yaser Masoomi ، mino baghery ، Ali morsali

Abstract

Two new porous cobalt based metal-organic frameworks, [Co6(oba)5(OH)2(H2O)2(DMF)4]n·5DMF (TMU-10) and [Co3(oba)3(O)(Py)0.5]n·4DMF·Py (TMU-12) have been synthesized by solvothermal method using a nonlinear dicarboxylate ligand. Under mild reaction conditions, these compounds exhibited good catalytic activity and reusability in oxidative desulfurization (ODS) reaction of model oil which was prepared by dissolving dibenzothiophene (DBT) in n-hexane. FT-IR and Mass analysis showed that the main product of DBT oxidation is its corresponding sulfone, which was adsorbed on the surfaces of catalysts. The activation energy was obtained as 13.4 kJ /mol.