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Mohammad Yaser Masoomi

Mohammad Yaser Masoomi

Academic rank: Assistant Professor
ORCID: https://orcid.org/0000-0003-1329-5947
Education: PhD.
ScopusId: 36927960900
Faculty: Science
Address: Arak University
Phone:

Research

Title
Mechanosynthesis of new azine-functionalized Zn(II) Metal-organic frameworks for improved catalytic performance
Type
JournalPaper
Keywords
Mechanosynthesis, azine-functionalized
Year
2014
Journal Journal of Materials Chemistry A
DOI
Researchers Mohammad Yaser Masoomi ، Saeideh Beheshti ، Ali morsali

Abstract

Three 3D, porous Zn(II)-based metal-organic frameworks, TMU-4, TMU-5 and TMU-6, containing azine-functionalized pores, were readily and quickly prepared via mechanosynthesis. Catalytic performance of these MOFs and the effect of N-donor ligands with diverse basicity in Knoevenagel condensation reaction are investigated. Increasing the basicity of N-donor ligands leads to improvement in catalytic activity. Results show that among the three compounds, TMU-5 has the highest catalytic activity upon increasing its basicity of azine function in N-donor ligand. These catalysts maintain their crystalline framework after reaction and are easily recycled.