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Mohammad Yaser Masoomi

Mohammad Yaser Masoomi

Academic rank: Assistant Professor
ORCID: https://orcid.org/0000-0003-1329-5947
Education: PhD.
ScopusId: 36927960900
Faculty: Science
Address: Arak University
Phone:

Research

Title
Selective CO2 Capture in Metal-Organic Frameworks with Azine-Functionalized Pores Generated by Mechanosynthesis
Type
JournalPaper
Keywords
CO2 Capture MOF
Year
2014
Journal CRYST GROWTH DES
DOI
Researchers Kyriakos C Stylianou ، Mohammad Yaser Masoomi ، Ali morsali ، Pascal Retailleau ، Daniel Maspoch

Abstract

Two new three-dimensional porous Zn(II)-based metal −organic frameworks, containing azine-functionalized pores, have been readily and quickly isolated via mechanosynthesis, by using a nonlinear dicarboxylate and linear N-donor ligands. The use of nonfunctionalized and methyl-functionalized N-donor ligands has led to the formation of frameworks with different topologies and metal−ligand connectivities and therefore different pore sizes and accessible volumes. Despite this, both metal −organic frameworks (MOFs) possess comparable BET surface areas and CO 2 uptakes at 273 and 298 K at 1 bar. The network with narrow and interconnected pores in three dimensions shows greater affinity for CO 2 compared to the network with one-dimensional and relatively large pores attributable to the more effective interactions with the azine groups.