2024 : 4 : 14
Mohammad Ali Bodaghifard

Mohammad Ali Bodaghifard

Academic rank: Associate Professor
ORCID: https://orcid.org/0000-0001-9732-4746
Education: PhD.
ScopusId: 6507703429
Faculty: Science
Address: Arak University
Phone:

Research

Title
Zeolite-based hybrid material as an efficient promoter in the green synthesis of mono/bisphthalazinones
Type
JournalPaper
Keywords
Green synthesis; heterogeneous catalysis; hybrid material; phthalazine-dione; zeolite
Year
2021
Journal SYNTHETIC COMMUN
DOI
Researchers Mahdia Hamidinasab ، Meysam Ghasemi ، Mohammad Ali Bodaghifard

Abstract

Hybrid structures containing organic-inorganic porous materials are of great interest as green, heterogeneous, and recyclable catalysts. In this study, a novel organic-inorganic hybrid material (Zeolite HY@DETA) via the surface-functionalization of the Zeolite HY was prepared. The structure of hybrid material was characterized using the Fourier-transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FE-SEM), Energy-dispersive X-ray spectroscopy (EDS), thermogravimetric analysis (TGA), and Brunauer–Emmett–Teller (BET) surface area analysis. Subsequently, the catalytic activity of this novel hybrid material was considered in the one-pot three-component synthesis of 3-amino-1-aryl-5,10-dioxo- 1H-pyrazolo[1,2-b]phthalazine-2-carbonitrile and some bis phthalazine- dione derivatives under green and environmentally benign conditions. The products were synthesized in excellent yields within a short reaction time and identified using elemental analysis, FT-IR, 1H NMR, and 13C NMR spectroscopies. This protocol avoids the use of harmful catalysts, toxic solvents, and harsh reaction conditions. Besides, the catalyst could be recycled for five reaction runs with a slight loss of catalytic activity.