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Fahime Parvizian

Fahime Parvizian

Academic rank: Associate Professor
ORCID: https://orcid.org/0000-0001-6112-0047
Education: PhD.
ScopusId: 26425215000
Faculty: Engineering
Address: Arak University
Phone:

Research

Title
Preparation and electrochemical characterization of polyaniline/activated carbon composites as an electrode material for supercapacitors
Type
JournalPaper
Keywords
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Year
2014
Journal Korean Journal of Chemical Engineering
DOI
Researchers Seyed mohsen Hosseini ، Abdolreza Moghadassi ، Fahime Parvizian ، Seyed Siavash Madaeni

Abstract

Polyaniline (PANI)/activated carbon (AC) composites were prepared by a chemical oxidation polymerization. To find an optimum ratio between PANI and AC which shows superior electrochemical properties, the preparation was carried out in changing the amount of added aniline monomers. The morphology of prepared composites was investigated by scanning electron microscopy (SEM) and transmission electron microscope (TEM). The structural and thermal properties were investigated by Fourier transform infrared spectra (FT-IR) and thermal gravimetric analysis (TGA), respectively. The electrochemical properties were characterized by cyclic voltammetry (CV). Composites showed a summation of capacitances that consisted of two origins. One is double-layer capacitance by ACs and the other is faradic capacitance by redox reaction of PANI. Fiber-like PANIs are coated on the surface of ACs and they contribute to the large surface for redox reaction. The vacancy among fibers provided the better diffusion and accessibility of ion. High capacitances of composites were originated from the network structure having vacancy made by PANI fibers. It was found that the composite prepared with 5 ml of aniline monomer and 0.25 g of AC showed the highest capacitance. Capacitance of 771 F/g was obtained at a scan rate of 5 mV/s