In this research, polycarbonate (PC) and acrylonitrile butadiene styrene (ABS) based heterogeneous cation exchange membranes modified by NiFe2O4 (Nickel Ferrite) nanoparticles were prepared by casting-solution techniques, and their morphological and electrochemical properties were studied.Ion exchange capacity, transport number, permselectivity and ionic flux were investigated.The results show that in membranes prepared with different percentages of nanoparticles, the ion exchange capacity and ionic flux increased toward the membranes without nanoparticles. By adding nanoparticles of nickel ferrite, due to the magnetic properties and absorption of these nanoparticles, and their accumulation around the resin, access to the functional group is reduced and the ion exchange capacity decreases and with the improvement of the path of the transfer channels increased of the flux.