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Akbar Mobinikhaledi

Akbar Mobinikhaledi

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-9732-7282
Education: PhD.
ScopusId: 6701730547
Faculty: Science
Address: Arak University
Phone:

Research

Title
Synthesis of bis-imidazole derivatives from 2,6-bis(4-formylbenzylidiene)-cycloalkanones
Type
JournalPaper
Keywords
aldol condensation, bis-imidazole, green chemistry, multicomponent reaction, solvent-free conditions
Year
2014
Journal Journal of the Iranian Chemical Research
DOI
Researchers Seyed Mohammad Bagher Hosseini Hosseini-Ghazvini ، Akbar Mobinikhaledi

Abstract

2,5-Bis(4-(4,5-bis(4-aryl)-1H-imidazol-2-yl)benzylidene)-cycloalkanones were synthesised by reacting 4,4′-(2-oxocycloalkane-1,3-diylidene) bis(methan-1-yl-1-ylidene) dibenzaldehydes, resulting from aldol condensation of terephthalaldehyde and cycloalkanones, with benzil and ammonium acetate. The structures of the products were then identified by FTIR, 1 H NMR, 13 C NMR and elemental analysis. The reaction conditions were optimised by varying the type and amount of catalyst, and temperature. The key advantages of this process are simple procedure, environmentally friendly conditions and good yield of products.