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Akbar Mobinikhaledi

Akbar Mobinikhaledi

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-9732-7282
Education: PhD.
ScopusId: 6701730547
Faculty: Science
Address: Arak University
Phone:

Research

Title
Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane/HOAc/KI system as a new and mild catalyst for efficient synthesis of 1H-benzimidazoles and 1H-benzothiazoles in water
Type
JournalPaper
Keywords
2-Aryl-1-arylmethyl-1H-benzimidazoles, 2-Aryl-1H-benzothiazoles, Condensation, Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane (DHPDMDO), KI, Aldehydes
Year
2014
Journal Iranian Journal of Catalysis
DOI
Researchers Kaveh Khosravi ، Akbar Mobinikhaledi ، Samira Kazemi ، davoud azarifard ، Payam Rahmani

Abstract

An efficient method has been developed for the catalysis of condensation of 1,2-phenylenediamines and 2-aminothiophenoles with different aldehydes into their corresponding 2-aryl-1H-benzimidazoles and 2-aryl-1H-benzothiazoles under mild condition. In this method, trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane (DHPDMDO)/HOAc/KI system was used as a novel and effective oxidant in water at room temperature with excellent results.