عنوان
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Ultrasonic assisted synthesis of two new coordination polymers and their applications as precursors for preparation of nano-materials
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نوع پژوهش
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مقاله چاپشده
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کلیدواژهها
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Coordination polymer, Sonochemistry, Calcination, Nanostructure
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چکیده
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Two new isostructural coordination polymers, [Zn3(Oba)4][Me2NH2)2].6DMF.3H2O (1) and [Cd3(Oba)4][Me2NH2)2].2DMF.2H2O (2), were synthesized using nonlinear dicarboxylate ligand, 4,4ʹ-oxybis(benzoic acid) (H2oba) and characterized by IR spectroscopy and single-crystal X-ray crystallography. Single-crystal X-ray data show that 1 and 2 are two-dimensional coordination polymers that can be extended to three-dimensional supramulecular networks by CH…O. These two new coordination polymers were also sonochemically synthesized while sonication time and power of irradiation influencing size and morphology of nano-structured compounds were also studied. Moreover, calcination of these coordination polymers creates ZnO and CdO nanostructures.
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پژوهشگران
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جان وانگ (نفر چهارم)، پیتر جانک (نفر سوم)، علی مرسلی (نفر دوم)، محمد یاسر معصومی (نفر اول)
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