مشخصات پژوهش

صفحه نخست /Ultrasonic assisted synthesis ...
عنوان Ultrasonic assisted synthesis of two new coordination polymers and their applications as precursors for preparation of nano-materials
نوع پژوهش مقاله چاپ‌شده
کلیدواژه‌ها Coordination polymer, Sonochemistry, Calcination, Nanostructure
چکیده Two new isostructural coordination polymers, [Zn3(Oba)4][Me2NH2)2].6DMF.3H2O (1) and [Cd3(Oba)4][Me2NH2)2].2DMF.2H2O (2), were synthesized using nonlinear dicarboxylate ligand, 4,4ʹ-oxybis(benzoic acid) (H2oba) and characterized by IR spectroscopy and single-crystal X-ray crystallography. Single-crystal X-ray data show that 1 and 2 are two-dimensional coordination polymers that can be extended to three-dimensional supramulecular networks by CH…O. These two new coordination polymers were also sonochemically synthesized while sonication time and power of irradiation influencing size and morphology of nano-structured compounds were also studied. Moreover, calcination of these coordination polymers creates ZnO and CdO nanostructures.
پژوهشگران جان وانگ (نفر چهارم)، پیتر جانک (نفر سوم)، علی مرسلی (نفر دوم)، محمد یاسر معصومی (نفر اول)