عنوان
|
Synthesis of Ferrite Nickel Nano-particles and Its Role as a p-Dopant in the Improvement of Hole Injection of an Organic Light-Emitting Diode
|
نوع پژوهش
|
مقاله چاپشده
|
کلیدواژهها
|
Znq2, NiFe2O4 nano-particles, XRD, SEM, UV–Vis, FT-IR, photoluminescence, energy level
|
چکیده
|
We fabricated an organometallic complex based on zinc ions using zinc complex as a fluorescent in organic light-emitting diodes (OLEDs). Also, the nano-particles of ferrite nickel were produced in a simple aqueous system prepared by mixing Ni(NO3)2, Fe(NO3)3 and deionized water solutions. The synthesized zinc bis (8-hydroxyquinoline) (Znq2) complex and NiFe2O4 nano-particles were characterized by using x-ray diffraction (XRD), ultraviolet–visible (UV–Vis), Fourier transform infrared spectroscopy (FT-IR) as well as photoluminescence spectroscopy analysis. Their energy level was also determined by some cyclic voltammetry (CV) measurements. The maximum green photoluminescence was observed at 565 nm. The nano-particles of ferrite nickel were utilized in preparation of OLEDs by blending of the magnetic nano-particles with PEDOT: PSS and Zn-complex solutions. The electrical and optical performance of prepared OLEDs with/without doped nano-particle was studied. The samples were configured into two structures: (1) Indium Tin Oxide (ITO)/ poly(3,4-ethylenedi-oxythiophene):poly(styrenesulfonate) (PEDOT:PSS)/Znq2/ (2-4-biphenylyl)-5-phenyl-oxadiazole (PBD)/aluminum (Al) and (2) ITO/PEDOT: PSS:NiFe2O4(NPs)/Znq2/PBD/Al. Obtained results showed that the current density and electroluminescence efficiency were increased and the turn-on voltage decreased (about 3 V) by using nano-particles into a PEDOT:PSS layer (Hole transport layer). Also, the electroluminescence efficiency was decreased by incorporating magnetic nano-particles into a Zn-complex layer (emissive layer). It was found that utilizing NiFe2O4 nano-particles caused an increase of hole-injection layer conductivity effectively and a decrease of the turn-on voltage.
|
پژوهشگران
|
زهرا شاهدی (نفر چهارم)، سیدمحسن حسینی (نفر سوم)، محمدرضا جعفری (نفر دوم)، مریم نوری (نفر اول)
|