مشخصات پژوهش

صفحه نخست /N-Propylcarbamothioyl ...
عنوان N-Propylcarbamothioyl benzamide complex of Bi(III) supported on superparamagnetic Fe3O4/SiO2 nanoparticles as a highly efficient and magnetically recoverable heterogeneous nanocatalyst for the one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones/thiones (DHPMs) via the Biginelli reaction
نوع پژوهش مقاله چاپ‌شده
کلیدواژه‌ها Biginelli reaction  3, 4-Dihydropyrimidin-2(1H)-ones/thiones  Heterogeneous catalysts  Bismuth (III) complex  Fe3O4/SiO2  Solvent-free conditions
چکیده The N-propylcarbamothioyl benzamide complex of Bi(III) immobilized on silica coated Fe3O4 magnetic nanoparticles has been prepared as a highly effi- cient and recyclable heterogeneous nanocatalyst using simple processes for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones/thiones via a one-pot multicomponent condensation reaction of urea, aldehydes and b-dicarbonyl compounds under solvent-free conditions at 100 C. The structural and magnetic properties of the nanocatalyst were characterized using various techniques such as Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, thermogravimetric analysis, vibrating sample magnetometery and elemental analyses. Also, this nanocatalyst can be easily recovered by a magnetic field and reused for subsequent reactions for at least five times without deterioration in catalytic activity.
پژوهشگران علیرضا خواجه امیری (نفر سوم)، اکبر مبینی خالدی (نفر اول)، ن فروغی فارا (نفر دوم)