عنوان
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An effective and mild oxidative aromatization of isoxazolines and 2-pyrazolines by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane promoted by ammonium iodide in water/MeCN
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نوع پژوهش
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مقاله چاپشده
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کلیدواژهها
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Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane; Pyrazoles; Isoxazoles.
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چکیده
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In this work, trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxalane (DHPDMDO)/NH I has been used as, powerful, nearly green, effective and inexpensive oxidant for oxidative aromatization of isoxazolines and 2-pyrazolines to corresponding isoxazoles and 2pyrazoles in the presence of catalytic amount of acetic acid at room temperature in water/MeCN. All products were obtained in high yields and good purity within short time by an easy work-up.
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پژوهشگران
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سمیرا کاظمی (نفر سوم)، کاوه خسروی (نفر دوم)، اکبر مبینی خالدی (نفر اول)
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