2024 : 5 : 20
Seyed mohsen Hosseini

Seyed mohsen Hosseini

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-3974-5312
Education: PhD.
ScopusId: 55897505600
Faculty: Engineering
Address: Arak University


Novel electrodialysis cation exchange membrane prepared by 2-acrylamido-2-methylpropane sulfonic acid; heavy metal ions removal
Cation exchange membrane; Hydrogel; Porous structure; Desalination; Heavy metal removal
Journal Journal of Hazardous Materials
Researchers Mahsa Nemati ، Seyed mohsen Hosseini ، Meisam Shabanian


In the present work a novel heterogeneous cation exchange membrane (CEM) composed of polyvinyl chloride (PVC) and 2-acrylamido-2-methylpropane sulfonic acid based hydrogel (AMAH) was prepared.The membranes were fabricated with different fractions of AMAH to optimize the performance in desalination. The hydrogel was characterized by FT-IR to prove the successful synthesis. The membrane properties such as permselectivity, ionic permeability, flux, water content, electrical resistance,morphology, contact angle and dimensional stability were evaluated. Modified membranes showed acceptable dimensional stabilities, more hydrophilic surface, higher water content and porosity. SEM images revealed the formation of a more porous membrane structure. Membrane permselectivity and transport number showed a relatively constant then decreasing trend in Na+and Ba2+solutions. The experimental results showed that the incorporation of AMAH into the PVC matrix obviously improved ionic permeability and flux of Na (∼9%) and Ba (∼23%). Membrane electrical resistance was declined about 36% by adding AMAH in the membrane structure. Membranes’ performance in potassium and heavy metal ions removal showed a remarkable separation capacity of K+(99.9%), Pb2+(99.9%) and Ni2+(96.9%). Membranes showed desirable potential for scaling removal.