Synthesis of bio-based polyamide/acid-functionalized multiwalled carbon nanotube nanocomposites (PA/FCNT NCs) is reported in this investigation. New aliphatic–aromatic bio-based vpolyamide (PA) was synthesized through direct polycondensation reaction between bio-based diacid derived from a renewable resource; vanillin and diamine containing ether linkages. To obtain a homogeneous dispersion of multiwalled carbon nanotubes (MWCNTs) in the PA matrix, acid-functionalized MWCNTs (FCNTs) were used and PA nanocomposites with three different FCNT contents (1, 5 and 7 wt%) were prepared. The resulting NCs were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and thermogravimetric analysis (TGA).