Newhigh lithiumion conductor glass–ceramicswith NASICON-type structure (Li1 +x + yAlxCryGe2 − x − y(PO4)3, x + y = 0.5) were synthesized using melt-quenching method and converted to glass–ceramics through heat treatment. Influence of addition of different concentrations of aluminum and chromium in LiGe2(PO4)3 glassceramic was investigated. Substitution of Ge4+ ions by Al3+ and Cr3+ ions induced more Li+ ions in A2 vacant sites and also changed the unit cell parameters and resulted in ionic conductivity improvement of glass–ceramics. The glass–ceramics were characterized by X-ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Energy-Dispersive X-ray spectroscopy (EDX), Differential Scanning Calorimetry (DSC), Complex Impedance Spectroscopy (CIS) and cyclic voltammetry (CV). The highest lithium ion conductivity of 6.65 × 10−3 S/cm was obtained for x = 0.4 and y = 0.1 (Li1.5Al0.4Cr0.1Ge1.5(PO4)3) crystallized at 850 °C for 8 h with minimum activation energy of 0.292 eV.
