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Seyed mohsen Hosseini

Seyed mohsen Hosseini

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-3974-5312
Education: PhD.
ScopusId: 55897505600
Faculty: Engineering
Address: Arak University
Phone:

Research

Title
High selective heterogeneous cation exchange membrane modified by l-cysteine with enhanced electrochemical performance
Type
JournalPaper
Keywords
Cation exchange membranes, Ionic clusters, l-Cysteine, Intensified electrochemical property, Lead ion removal
Year
2020
Journal IONICS
DOI
Researchers Elham Jashni ، Seyed mohsen Hosseini

Abstract

This research focuses on the formation of ionic clusters and the transport properties of metal ions through electrodialysis heterogeneous cation exchange membrane modified by l-cysteine as a polar additive. The molecular electrostatic potential of l-Cyst and resin particle showed appropriate reactive sites for electrophilic and nucleophilic attacks. Furthermore, the calculated interaction energy confirmed the presence of strong interactions between the l-Cyst molecule and the resin particle. Elemental mapping, scanning electron microscopy (SEM), and scanning optical microscopy (SOM) images of the blended membranes represented a relatively uniform surface and particle distribution. Membrane water uptake and surface hydrophilicity were enhanced in the presence of l-Cyst. The blended membranes demonstrated high selectivity (> 99%), lower electrical resistance (< 5–6 Ω cm2), and better ionic permeability compared to the bare membrane. The blended membranes (HCEM–2.0 wt% l-Cyst) showed higher dialytic rate, lower energy consumption, and current efficiency in Pb2+ ion removal from water compared to the bare sample.