2024 : 4 : 15
Seyed mohsen Hosseini

Seyed mohsen Hosseini

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-3974-5312
Education: PhD.
ScopusId: 55897505600
Faculty: Engineering
Address: Arak University
Phone:

Research

Title
Electrodialysis heterogeneous ion exchange membranes modified by SiO2 nanoparticles: fabrication and electrochemical characterization
Type
JournalPaper
Keywords
desalination, electrodialysis, ion exchange, mixed matrix, physicochemical characterization, SiO2 nanoparticles
Year
2016
Journal Water Science & Technology
DOI
Researchers Seyed mohsen Hosseini ، Zahra Ahmadi ، Mahsa Nemati ، Fahime Parvizian ، Seyed Siavash Madaeni

Abstract

In the current study mixed matrix heterogeneous cation exchange membranes were prepared by solution casting technique. The effect of SiO2 nanoparticles in the polymeric solution on the physicochemical properties of prepared membranes was studied. Scanning optical microscope images showed uniform particle distribution and relatively uniform surfaces for the prepared membranes. The membrane water content was reduced by silica nanoparticles in the membranes’ matrix. The membrane ion exchange capacity, membrane potential, transport number and selectivity were improved initially by an increase of SiO2 nanoparticles concentration up to 1%wt in prepared membranes and then showed a decreasing trend with a further increase in additive ratio from 1 to 4%wt. The ionic permeability and flux were also decreased initially by an increase of silica nanoparticles concentration up to 0.5%wt in the membrane matrix and then increased again with a further increase in nanoparticles concentration from 0.5 to 4%wt. Moreover, the results exhibited that using silica nanoparticles in the membrane matrix caused an obvious decrease in areal electrical resistance. The opposite trend was found for membrane mechanical strength using SiO2 nanoparticles.