2024 : 4 : 14
Mohammad Ali Bodaghifard

Mohammad Ali Bodaghifard

Academic rank: Associate Professor
ORCID: https://orcid.org/0000-0001-9732-4746
Education: PhD.
ScopusId: 6507703429
Faculty: Science
Address: Arak University


High‑efficient synthesis of 2‑imino‑2H‑chromenes and dihydropyrano[c]chromenes using novel and green catalyst (CaO@SiO2@AIL)
Ionic liquid · Eggshells waste · Biocatalyst · 2-Imino-2H-chromenes · Dihydropyrano[c]chromenes
Journal Research on Chemical Intermediates
Researchers Fatemeh Sameri ، Akbar Mobinikhaledi ، Mohammad Ali Bodaghifard


In this work, 1,3,5,7-tetraazaadamantan-1-ium chloride (AIL) functionalized silicacoated calcium oxide hybrid nanocatalyst (CaO@SiO2@AIL) as a novel, efficient, green and recyclable heterogeneous ionic liquid catalyst was synthesized. Catalytic activity of the CaO@SiO2@AIL hybrid nanoparticles was investigated for synthesis of the pharmaceutically valuable 2-imino-2H-chromene and dihydropyrano[c] chromene derivatives. A wide range of amines and aromatic aldehydes containing either electron-withdrawing or electron-donating substituent were examined using optimized conditions to produce the desired products. 2-Imino-2H-chromenes were synthesized under solvent-free condition, and dihydropyrano[c]chromenes were prepared in aqueous medium as green conditions within short reaction times, high yields and using easy workup procedures. Structure confirmation and surface properties of the core/shell hybrid nanoparticles were considered via Fourier transform infrared spectroscopy, X-ray powder diffraction, scanning electron microscope, energy-dispersive X-ray spectroscopy, WDS map scan, thermogravimetric and elemental analyses. This IL-supported heterogeneous nanocatalyst can be reused at least six times without considerable loss of its performance.