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Kaveh Khosravi

Kaveh Khosravi

Academic rank: Associate Professor
ORCID: https://orcid.org/0000-0002-5671-944X
Education: PhD.
ScopusId: 26648894200
Faculty: Science
Address: Arak University
Phone:

Research

Title
Efficient oxidative dehydrogenation of dihydropyrimidinones and thiocyanation of aromatic compounds using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane as the oxidant
Type
JournalPaper
Keywords
Dehydropirimidinones, Oxidative dehydrogenation, Thiocyanation, 1,1,2,2-Tetrahydroperoxy-1,2-diphenylethane, Pyrimidinones
Year
2019
Journal ORGANIC CHEMISTRY RESEARCH
DOI
Researchers Kaveh Khosravi ، Amir Azizi ، Shirin Naserifar

Abstract

A new, efficient and mild approach for the oxidative dehydrogenation of dihydropyrimidinones and thiocyanation of aromatic compounds using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane (THPDPE) as a terminal oxidant was developed. Initially, various substrates bearing different electron-donating and electron-releasing functionalities were synthesized, and next under the optimized reaction conditions the desired products were yielded after an easy work-up. All of the reactions proceeded in short reaction times, and 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane (THPDPE) proved its potential to yield the desired products in high yields.