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Kaveh Khosravi

Kaveh Khosravi

Academic rank: Associate Professor
ORCID: https://orcid.org/0000-0002-5671-944X
Education: PhD.
ScopusId: 26648894200
Faculty: Science
Address: Arak University
Phone:

Research

Title
Cesium nitrate: As an efficient catalyst for synthesis of gem-dihydroperoxides from aldehydes and ketones using aqueous 30% H2O2
Type
JournalPaper
Keywords
: gem-dihydroperoxide; aldehyde; ketones; cesium nitrate; hydrogen peroxide
Year
2015
Journal Cogent Chemistry
DOI
Researchers Kaveh Khosravi

Abstract

Gem-dihydroperoxides (DHPs), as key intermediates of aldehydes and ketones, are important precursors in synthesis of anti-malaria drugs and have been used as a solid and powerful oxidant in many oxidation organic reactions. For the importance of gem-DHPs, in this work, cesium nitrate has been used as an efficient and commercially available solid catalyst for catalysis peroxidation of aldehydes and ketones to corresponding gem-DHPs by 30% aqueous hydrogen peroxide at room temperature. The reactions carry on with short time and the products were obtained in excellent yields and high purity. In all reaction, no by-product was observed. This methodology is new, easy, effective, and usable.