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Hamid Khanmohammadi

Hamid Khanmohammadi

Academic rank: Professor
ORCID: https://orcid.org/0000-0001-5600-4738
Education: PhD.
ScopusId: 22734138900
HIndex:
Faculty: Science
Address: Arak University
Phone:

Research

Title
A new trinuclear N–N bridged Cu(II) complex with an asymmetric Schiff base ligand derived from hydrazine
Type
JournalPaper
Keywords
Trinuclear copper complex Schiff base ligands Magnetic properties Hydrazine Asymmetric ligands
Year
2017
Journal POLYHEDRON
DOI
Researchers samira gholizadedogahe ، Hamid Khanmohammadi ، Carolina Sanudo

Abstract

In this paper we report the synthesis of an asymmetric Schiff base ligand derived from hydrazine and its Cu(II) trinuclear coordination complex, [Cu3(HYDRAV)2Cl2] (HYDRAV-Cu). The ligand HYDRAVH2 and the Cu(II) complex HYDRAV-Cu have been crystallographically characterized. HYDRAVH2 contains a fluorescent naphthyl group and emission properties of both HYDRAVH2 and HYDRAV-Cu are reported. The magnetic properties of HYDRAV-Cu have been investigated. Hydrazine is an excellent precursor for asymmetric Schiff base ligands that afford antiferromagnetic coupling as shown here for HYDRAV-Cu.