2024 : 4 : 16
Akbar Mobinikhaledi

Akbar Mobinikhaledi

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-9732-7282
Education: PhD.
ScopusId: 6701730547
Faculty: Science
Address: Arak University
Phone:

Research

Title
Zn complexed on CaO coated with walnut husk extract as an efficient and reusable catalyst for the green synthesis of benzylpyrazolyl coumarin derivatives
Type
JournalPaper
Keywords
CaO@walnut husk@ZnO, nanoparticles, Biocatalyst, Benzylpyrazolyh derivatives
Year
2022
Journal Reaction Kinetics, Mechanisms and Catalysis
DOI
Researchers maryam hamzeh neyaee ، mojghan ahdi ، Fatemeh Sameri ، Akbar Mobinikhaledi

Abstract

In the present work, the novel CaO@walnut husk@ZnO nanoparticles were successfully synthesized by immobilization of Zn (II) on walnut husk extract-coated CaO nanoparticles using a simple and clean procedure. The structure and characterization of CaO@walnut husk@ZnO nanoparticles was properly investigated by Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and thermogravimetric analysis techniques (TGA). Furthermore, some of benzylpyrazolylby coumarin derivatives as an important heterocyclic compounds were synthesized in good to high yields by using the related starting materials in the presence of the prepared CaO@walnut husk@ZnO nanoparticles as a high efficient catalyst. The structure of all synthesized products was well characterized by FT-IR, 1H- and 13C-NMR data. This clean procedure offers some advantages such as the use of a green and cheap biocatalyst (prepared from walnut husk waste and eggshells waste) short reaction times, simple workup and high yield of products.