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Akbar Mobinikhaledi

Akbar Mobinikhaledi

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-9732-7282
Education: PhD.
ScopusId: 6701730547
Faculty: Science
Address: Arak University
Phone:

Research

Title
High‑efficient synthesis of 2‑imino‑2H‑chromenes and dihydropyrano[c]chromenes using novel and green catalyst (CaO@SiO2@AIL)
Type
JournalPaper
Keywords
Ionic liquid · Eggshells waste · Biocatalyst · 2-Imino-2H-chromenes · Dihydropyrano[c]chromenes
Year
2020
Journal Research on Chemical Intermediates
DOI
Researchers Fatemeh Sameri ، Akbar Mobinikhaledi ، Mohammad Ali Bodaghifard

Abstract

In this work, 1,3,5,7-tetraazaadamantan-1-ium chloride (AIL) functionalized silicacoated calcium oxide hybrid nanocatalyst (CaO@SiO2@AIL) as a novel, efficient, green and recyclable heterogeneous ionic liquid catalyst was synthesized. Catalytic activity of the CaO@SiO2@AIL hybrid nanoparticles was investigated for synthesis of the pharmaceutically valuable 2-imino-2H-chromene and dihydropyrano[c] chromene derivatives. A wide range of amines and aromatic aldehydes containing either electron-withdrawing or electron-donating substituent were examined using optimized conditions to produce the desired products. 2-Imino-2H-chromenes were synthesized under solvent-free condition, and dihydropyrano[c]chromenes were prepared in aqueous medium as green conditions within short reaction times, high yields and using easy workup procedures. Structure confirmation and surface properties of the core/shell hybrid nanoparticles were considered via Fourier transform infrared spectroscopy, X-ray powder diffraction, scanning electron microscope, energy-dispersive X-ray spectroscopy, WDS map scan, thermogravimetric and elemental analyses. This IL-supported heterogeneous nanocatalyst can be reused at least six times without considerable loss of its performance.