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Akbar Mobinikhaledi

Akbar Mobinikhaledi

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-9732-7282
Education: PhD.
ScopusId: 6701730547
Faculty: Science
Address: Arak University
Phone:

Research

Title
Synthesis ofanovel Pd supported polymeric magnetic nanoparticles withurea-pyridine bridge: application asanecient catalyst fortheC–C andC–N bond formationwith urea‑pyridine bridge: application as an efficient catalyst for the C–C and C–N bond formation
Type
JournalPaper
Keywords
C–C coupling • C–N coupling • Magnetic nanoparticle • Polymeric magnetic nanoparticles • Sonogashira reaction • Suzuki reaction • 3‐(Triethoxysilyl) propylisocyanate
Year
2020
Journal JOURNAL OF POROUS MATERIALS
DOI
Researchers Fereshteh Heydari ، Akbar Mobinikhaledi ، Mohammadali Zolfigol

Abstract

Here a novel Pd supported polymeric magnetic nanoparticles with urea-pyridine bridge (denoted as Fe3O4@/Urea-Pyridine/ Pd) was synthesized and characterized. The Fe3O4@/ Urea-Pyridine/Pd nanocatalyst was synthesized via a four steps process by using Fe3O4 nanoparticles, 3‐(triethoxysilyl) propylisocyanate (TESPIC), 2,6 bis(propyl-triethoxysilylureylene) pyridine (BPS) and palladium chloride. The synthesized polymeric Fe3O4@/ Urea-Pyridine/Pd nanocatalyst was analyzed through different analytical techniques, including FT-IR, NMR, XRD, VSM, TGA, DTA, ICP, FESEM, EDX, and BET. The described palladium supported polymeric magnetic nanoparticles with urea-pyridine bridge (Pd-MNPs) was used for the C–C and C–N coupling of phenylboronic acid with various amines and aryl halides in DMF as well as Sonogashira and Suzuki reactions in aqueous solution. Also, the Fe3O4@/ Urea-Pyridine/Pd nanocatalyst exhibited high structural stabilityand excellent recyclability.