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Akbar Mobinikhaledi

Akbar Mobinikhaledi

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-9732-7282
Education: PhD.
ScopusId: 6701730547
Faculty: Science
Address: Arak University
Phone:

Research

Title
Preparation and characterization of a novel host (zeolite NaY)/ guest (copper(II) complex of a new bidentate Schiff base ligand) nanocomposite material (HGNM): a comparison between catalytic reactivity of free and encapsulated complexes in oxidation of benzyl alcohol and aldol condensation
Type
JournalPaper
Keywords
Zeolite NaY. Encapsulation. Schiff base complex. Flexible ligand method. Aldol condensation. Oxidation of benzyl alcohol
Year
2014
Journal JOURNAL OF POROUS MATERIALS
DOI
Researchers Akbar Mobinikhaledi ، Mojgan Zendehdel ، Parvin Safari

Abstract

A copper(II) complex of 4-((E)-(4-(1H-benzo[d]imidazol-2-yl)phenyl)diazenyl)-2-((E)-(4-hy-droxyphenylimino) methyl)phenol (HL) was encapsulated in zeolite NaY by flexible ligand method. The structure of encapsulated complex was characterized by spectroscopic (electronic and FT-IR), XRD, TGA, BET and elemental analysis data. Furthermore, catalytic activity of the neat and encapsulated complexes was studied in oxidation of benzyl alcohol and aldol condensation. The encapsulated complex was more reactive and stable than the corre-sponding free complex. Nanocomposite material was enough stable to be reused for several times. Finally, the reaction parameters were optimized for oxidation of benzyl alcohol and aldol condensation.