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Akbar Mobinikhaledi

Akbar Mobinikhaledi

Academic rank: Professor
ORCID: https://orcid.org/0000-0002-9732-7282
Education: PhD.
ScopusId: 6701730547
Faculty: Science
Address: Arak University
Phone:

Research

Title
Flexible ligand synthesis and characterization of a host (a copper(II) tetradentate Schiff base)/guest (zeolite NaY) nanocomposite material: an efficient and reusable catalyst for the selective hydroxylation of phenol
Type
JournalPaper
Keywords
Host–guest nanocomposite material Heterogeneous and reusable catalyst Flexible ligand method Selective hydroxylation Phenol
Year
2015
Journal Reaction Kinetics, Mechanisms and Catalysis
DOI
Researchers Seyed Mohammad Bagher Hosseini Hosseini-Ghazvini ، Parvin Safari ، Akbar Mobinikhaledi ، Mojgan Zendehdel

Abstract

A copper(II) complex of 2,2′-(((butane-1,4-diylbis(oxy)) bis(2,1-phenylene))bis(azanylylidene)) bis(methanylylidene))diphenol (H2L) was successfully encapsulated in the supercages of zeolite NaY by the flexible ligand method. The structure of this compound was identified by physico-chemical and spectroscopic methods. The selective hydroxylation of phenol was catalyzed using the free and encapsulated complexes. The results illustrated that the catalytic activity and stability of the complex was increased by encapsulation. Furthermore, the optimum reaction conditions were obtained. The kinetics of the reaction was also studied at different temperatures. The encapsulated complex is stable enough and it could be reused several times.